Tomoyo
and Kinomoto Sakura are best friends, obviously. They met one day when Tomoyo first transferred to class. While she was doing her homework, she made a mistake and needed an eraser. ^^;;; Noticing that, Sakura gladly gave Tomoyo her eraser. At the end of class, Tomoyo gave Sakura back her eraser, but Sakura told Tomoyo that she can keep it. This was how they became friends. Tomoyo cherishes Sakura's eraser. How else would she have met Sakura? It's one of her most prized possessions. She keeps it in a wooden box with a locked key. To Sakura, Tomoyo is just her closest friend, but to Tomoyo, Sakura may be her love interest. Although Tomoyo had admitted that she loved Sakura more than a friend in the manga, her love for Sakura might have been just a strong sense of lust.
Before
Eriol was introduced into the series, Li Meiling was always with Syaoran, or most of the time. When Sakura and Syaoran were together somewhere, Meiling and Tomoyo are the ones together. During card quests, Meiling and Tomoyo, who are both magic-less, stick together and watch each other's backs, while making sure Sakura and Syaoran are okay, too. I'd say Meiling and Tomoyo are wonderful friends. They have conversations together every now and then. Meiling also slept over at Tomoyo's mansion before. Whenever Meiling needed advice or a shoulder to cry on, she would go over to Tomoyo. For example, when Meiling was heartbroken because Syaoran loved Sakura more than her, Meiling couldn't stop crying. Meiling wanted to hate Sakura, but she couldn't because Sakura was also her friend, so Meiling just sat there, weepign in Tomoyo's lap, while Tomoyo stroked her hair comfortingly. Even so, they're also the ones who form great plans to try and get Syaoran and Sakura to admit their feelings for each other.
Li Syaoran
and Tomoyo are quite good friends. Syaoran saved Tomoyo a few times during card quests, and I know Tomoyo couldn't have been more grateful. Syaoran even blushed a few times because of Tomoyo. Of course, this isn't a sign of love. Syaoran is obviously a bit "taken back" from Tomoyo's kindness. The only other girls who've ever been so kind towards him was Sakura and Meiling. Also, Tomoyo is like a younger sister to him. Whenever Syaoran blushes around Tomoyo, instead of mentioning it and embarassing him even more, she would just smile or let out a small giggle. You can find Tomoyo giving Syaoran advice when he's troubled. Tomoyo, along with Meiling, was one of the first people to realize that Syaoran loved Sakura, and vice versa. But, instead of telling them both that they felt the same way about each other, she decides to give them both advice and help both of them to admit their feelings for each other. Even though Syaoran took away Sakura from Tomoyo, she would still help them get together. So selfless... ;__;
During the second season of CCS, Hiiragizawa Eriol is the new transfer student from England. He sits right behind Tomoyo in class. By the time he arrives, Meiling already went home to Hong Kong. So, instead of Sakura, Syaoran, Tomoyo, and Meiling always together, you'll see Sakura, Syaoran, Tomoyo, and Eriol together at carnivals, at school, etc. ^^;; Although Eriol and Tomoyo do not interact too much in both the anime and manga, I think they make a cute couple! Yesh, another ExT fan~ :x They look so cute together, and their personalities are so much alike! Even if their coupling is most likely not possible, a fangirl can still dream, can't she? XD; Anyway, during some of their interactions, they're always so formal with each other. Like Tomoyo, Eriol is also very observant, and he because he's observant, he notices her observant skills as well. He compliments her a few times and like Tomoyo and Meiling, who come up with plans ot get Sakura and Syaoran to admit their feelings for each other, they Eriol and Tomoyo do the same as well.
Kyaaaa~~
Tomoyo and Kero~~ <3 Tomoyo and Kero get along very well. Keroberos, Kero's true form, saves Tomoyo a few times during the card quests. They also chat a lot about Sakura and are usually together having tea, or a snack. =] Sometimes Tomoyo won't be there to tape Sakura while she captures a clow card, but Kero-chan is usually there. So, Kero is willing to tell Tomoyo all about what happened, while Tomoyo tapes him. During the adorable Sakura and Syaoran "moments," Tomoyo and Kero can be found hiding in a bush or somewhere, taping them. (Well, actually, Kero would be griding his teeth at Syaoran and Tomoyo would be doing the taping. XD) Everytime Tomoyo comes over to Sakura's house, he always appears to be very glad to see her. (Who can help it? She's such a sweetie! :D) Kero, being such a huge food maniac, always becomes upset everytime Sakura would eat yummy food without him. However, Tomoyo always remembers to save him a piece of the food. ^-^
When Tomoyo isn't with Sakura, you'll find her with Chiharu, Naoko, or Rika. They're all friends of Tomoyo's, as well as Sakura's. They chat a lot, and admire things that 10 years olds admire. There's really nothing much else to say. They just do what most friends do.
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